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premature exfoliation 

The tendency of certain trees to display autumn colors in August.
Amy was depressed when the oak exhibited premature exfoliation in the middle of August.

exfoliate 

Actually means to clean yourself in such a way to remove dead skin cells and then remoisturize the skin.

Now that the real definition is out of the way, let's do an Urban definition!

When a man is pounding a chick doggy-style near a toilet. The man grabs the chick by the hair and shoves her head into the toilet, flushing it and giving her a swirley! Now that the face is cleansed, it must be moisturized. The guy then yanks her head out of the the toilet by her dripping wet hair, pulls his dick out of her, and blows his load all over her face.
I'll exfoliate Mel Gibson, how 'bout that?

exfoliate 

This new soap has shards of glass in it, so it really exfoliates.
exfoliate by BubDZombie July 10, 2009

exfoliation 

Sex through the belly button
I will use exfoliation to exfoliate your taste buds
exfoliation by mr.exfoliator October 30, 2013

exfoliate 

To come out of a shell and do something different to express yourself.
From "What Women Want" (Mel Gibson and his screen daughter in bathroom, Mel in pantyhose)

Daughter: "Dad! What are you doing??"
Mel: "I'm...ah...exfoliating"
exfoliate by SuperMan9856 March 14, 2004

Exfoliating Mask 

When you cum on a girls face then immediately wrap her face up in plastic wrap.
That girl had some acne so I give her an exfoliating mask.
Exfoliating Mask by real quick September 7, 2009