Free from prior obligations along with enough motivation to take the neccessary steps in which to engage in sharing ones time with a friend or colleague.
It's a word put together from Chillin' and Relaxing. It actually means the same. If somebody should cool down you could say he or she has to relax or has to chill out. If you decide not to choose between these to, or you haven't made a decision while you already have to say the word, you say 'Chillax'.