When someone of the opposite sex (usually a female), teases you, but does not want a relationship of any sort - she is unfuckable, and impossible to win over, hence she's "unfuckwinable".
when you're holding up your phone and making faces at it, as though you are taking a selfie, but you're really taking a picture of the person across from you or the wall or anything else that seems interesting but you don't want to be caught dead taking a picture of.
This action is often made more convincing by wiggling the eyebrows or opening the mouth, to pretend you're trying to get a Snapchat filter to work.