Basically, this term means that you can't getsomething any cleaner (or purer) than it is. It's also meant as a compliment by saying that somebody's mother is not a skanky whore or streetwalker. This term appeared in the young adult edition of the novel adaptation of the 1979 sci-fi thriller"Alien".
George the janitor tidied up the restroom so well it's not simply spic and span, it's as clean as your mother's reputation.
Someone who is addicted to obtaining money and building wealth. A money addict and fanatic. Breadheads often work more than one full-time job, and some even participate in illicit activities to "obtain the bread".