As with 'awesome sauce', this is an exclamation or reserved sign of approval. The difference in this case being that the exclamation comes in the form of both complimenting and envying the guy wearing a Green Jacket.
Steve: So'd anything happen with that chick you met at the bar last weekend?
Someone who is addicted to obtaining money and building wealth. A money addict and fanatic. Breadheads often work more than one full-time job, and some even participate in illicit activities to "obtain the bread".