Just posting this definition to point out that the expression predates Family Guy by decades, having at least appeared in Paul Schrader's 1971 essay "Notes on Film Noir".
Someone who is addicted to obtaining money and building wealth. A money addict and fanatic. Breadheads often work more than one full-time job, and some even participate in illicit activities to "obtain the bread".
I don't buy the schmegegge about Morty sleeping with Moira.
His version of the story was pure schmegegge.
The whole schmegegge was made up to get Liz a little bit of attention.