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Goofy Older Brother Syndrome 

A condition most commonly pertaining to young men wherein every female he is attracted to automatically kicks him to the friend zone because she thinks of him as an older brother. This often occurs when a girl mistakes being a gentleman or a nice guy for being a pussy. Some girls go so far as to designate these poor bastards as their go-to "Shoulders to Cry on" when they repeatedly get shit on by the assholes they do date. -See the film "Sexdrive"
"Dude did you get anywhere with her last night?"

"No man, she told me it will never happen cause I'm too much like a brother to her and she doesn't want to ruin our friendship. I must have Goofy Older Brother Syndrome."
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love you like a brother 

A phrase commonly used by girls to blow off guys they are friends with or dating. It is especially painful for the latter, due to the fact that they have often sacrificed a lot and strong feelings for the girl.
Girl: I'm sorry I haven't been talking to you...I think I love you like a brother.
Boy: I have nothing...#crushed

PLAY BROTHER 

The undercover love interest of a woman who is engaging another man outside her marriage or relationship. To her husband, this extra guy is a friend (play brother), when the truth is she and this "play brother" may have been intimate in the past, but the relationship did not work out.
He's just my play brother - there is nothing up between him and I.
PLAY BROTHER by D.E.L. December 30, 2011

Chemical Brother 

A close friend with whom you take mind altering substances. This frienship is often strenghtened by a strong psychic connection, caused by hallucinogenic and euphoric drugs.
a.k.a. "Drug Buddy"
When I was having a bad trip, My chemical brother John came along and helped me relax.
Chemical Brother by CRWK April 5, 2006

Big Brother 

Big Brother by Googlesoft January 16, 2009

paper bag brother 

man with a great body but fugly face, making a paper bag over the head necessary for sex. Male equivalent of butterface.
Her boyfriend is nice enough, but he's a paper bag brother all the way.

gutter slut brother fucker 

just the same as a gutter slut but one who will have a threesome with her boy friend and his brother
That gutter slut brother fucker stole my keys , pissed my seat, and wrinkled my randy travis poster.