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This phrase is never meant to be taken literally. No-one really injects coffee directly into their blood stream. Caffeine is the main ingredient of coffee, and gives us a feeling of satisfaction. It is simply a joking expression which refers to an intense love, or even addiction, to coffee.
I'm going nuts - If I don't shoot caffeine intravenously soon I'm going to fall out of my tree!

When I was 13 I had my first coffee, and I've been practically shooting caffeine intravenously ever since!
by Brother Ramon July 8, 2011
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Cum Shoot

when you are ejaculating / cumming over your partner, and instead of just cumming, you hold and aim your penis at a particular part of your partners body and 'shoot' your cum on that body part
After Mandy sucked me off last night I gave her a 'Cum Shoot' all over her left breast
by Hanker Chooy February 24, 2009
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shoot the breeze

Refers to where you sit quietly behind a big clueless dude who's eagerly chowing down on a huge plate of baked beans, "bide your time", and then fire off a starter-pistol just as said dude is starting to "rip one", thus igniting the unsuspecting dude's expelling methane and creating a humongous blowtorch-fireball out his ass. Extra points if (A) you loaded the gun with full-flash blanks --- both for a more spectacular effect and to better ensure that the muzzle-flash would indeed ignite the gas --- and (B) you chose a dude who usually has fairly "extended" farts instead of merely "little toots", so that any spectators can be treated to a real "light show" instead of just a brief flare-up.
Startled guy with a smoking pants-seat: Oh, Jeez Louize ---!!! When you fellas invited me over to your backyard barbeque to "shoot the breeze", I never expected that you'd mean it in a LITERAL sense!!
by QuacksO July 6, 2018
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Shooting Mars

It's when you aim a gun at Mars and shoot
"Hey, what are you up to?"
"Not much just shooting Mars, how about you?"
"Not much was just wondering what you were up to"
by CH L L L I N December 19, 2006
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shootin the j

Did you see cooper's arms yesterday?

Yeah! He must have been shootin the j
by Trevular October 23, 2008
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Shooting the gap

Verb;

Shooting the Gap refers to when one has the beegees and is sitting on the toilet releasing a massive amount of watery feces then suddenly they have to barf so they must "shoot the gap" between their privates and the bowl.
after a long night of burritos and liquor Kevin ran to the shitter and ended up shooting the gap. he barf all over his balls
by Jonnoguano August 6, 2011
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Real shootar

by remo November 2, 2003
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