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On your face 

The opposite to being off your face - being a responsible person who isn't intoxicated and doesn't endeavor/manage to somehow detach themselves from their complexion. If you are this, then you are on your face.
'I watched a documentary on BBC2 last night and ate some biscuits, I was completely on my face.'

'I'm going to get completely on my face tonight. Perhaps I'll read a book.'

'I was perfectly aware of getting home last night - I must have been completely on my face!'

'You look very normal, you must be on your face.'
On your face by UncleVernon April 10, 2015

On your face 

When something is on your face like a foot
On your face by Assume the position September 20, 2019

On your face 

When someone is making a promise or guarantee of something on their face (or honor, similar to giving their word).
If I loan you this money your telling me right now, on your face you will work for me for the next two weekends to make us even.

I gotta go straighten up my face with him by working this weekend and next.

wearing your ass on your face

wearing your ass on your face to forcibly implant your face into your ass similar to having a foot in your ass but much more severe
don't mess with officer smith or you will be wearing your ass on your face

Vomiting With A Smile On Your Face. 

A term usually meant to describe early users of heroin, they often "vomit with a smile on their face."
"Of course he was vomiting — that’s what people on heroin do, they vomit. It’s called ‘vomiting with a smile on your face’.”

"Oh, so he's a new junkie?"

"Yeah, vomiting with a smile on your face."

Sit on your face 

what a female say's when she wants oral sex