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The instance of having TWO wives.

the clue is in the Prefix 'Bi' - meaning two.
Having multiple wives is known as 'Polygamy' - not Bigamy
When John married Lisa, he was still legally married to Danielle, even though they were separated. Therefore John had committed Bigamy by marrying Lisa
Related Words

Big-ady-Bong 

A Big-ady-Bong is a specific measurement of bong size defined as exactly 1.9 grams. This term originated at the dawn of the Wiltshire Stoned Age where we gave Donnovan a bong this size that knocked him clean out for the rest of the night.
A respectful amount to get you from sober to high real fast.
"Fancy getting a bit fucked up tonight?"
"Yeah mate, I've started us all off, loaded myself a Big-ady-Bong"
Big-ady-Bong by The Sesh Gremlinz September 9, 2019

Bigadillion 

A one followed by a bigadillion zeros.
So large a number it sometimes exceeds infinity.
A hyperboly
That lady must way a Bigadillion pounds
Bigadillion by bigbad20 April 8, 2009
/noun/ -- The practice of fruadulently marrying more than one spouse
John married Jane without divorcing Mary and is thus guilty of the crime of Bigamy
Bigamy by Ronald A.King December 27, 2005
Bigamy is defined as having one wife too many.

See monogamy.
He practiced bigamy. He had one wife too many.
bigamy by Gandalf2349 December 20, 2005

Bigaysbian 

It's where your bi, gay, and a lesbian
I'm a bigaysbian
Bigaysbian by Patience Rose June 10, 2018