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The act of removing people from your 'friends list' on LiveJournal just to let them know you hate them, and you hope they die. In fact, you don't just hate them and hope that they die, but you hope they die a long, slow, painful, gut wrenching death. Preferably in a Turkish Prison that is overrun with skin eating mutant leeches.
I hate that person. I'm going to unfriend their ass.
Unfriend by yougot0wn3d November 5, 2004
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a coward's way of conflict management in the world of social networking; to disassociate from someone or something without attempt to resolve conflict or give notice.
I couldn't handle Deliliah's spiritual values so I unfriended her on Facebook.
The act of removing someone from your LiveJournal 'Friends List'.

One of the many ways to bitch slap someone on 'Teh Interweb'. Often happens in a domino effect, especially when one person doesn't like you - and they're good at influencing other people. With the right amount of pressure, one 'Unfriending', will lead to several.

But if that one person (ususually known as the queen bee) happens to 'Refriend' you, you'll notice the other drones will follow suit, because they are Borg, and have been 'assimilated'.

See minion, bitch, LiveJournal, slave, mindless, sheep, poser, drone, hive, insect.
"OMG. We hate that person this week. Didn't you know that?"
"No. Sorry. I didn't. Why do you hate them? What did they do??"
"Does it matter? WE JUST DO. Now UNFRIEND them from your Journal and get with the program!"
"OK!"
Unfriend by electronicbattleground November 8, 2004

Unfriendzy 

An unfriending frenzy, if you will.

The act of whipping through your facebook wall and unfriending every person that you realize you:

1. Don't actually know
2. Really dislike
3. Really dislike the things that they post (i.e. LMS, duckfaces, to be honest, or depressing posts about nobody in particular.)
Due to the high amount of annoying statuses and LMS's clouding my facebook wall, I partook on an unfriendzy, and reduced my friend count to 453 friends.
Unfriendzy by Tier17 July 25, 2012
To remove someone from your friends list as on Facebook, etc.
Joe and I are no longer tight so I unfriended him.

I shouldn't have agreed to her friend request so I'm just going to unfriend her.
Unfriend by Dunemoth January 28, 2009

Unfriendly 

Tries to shoot you with a bow and arrow
Lewis: He wasn't very friendly, he was rather agressive to us.

Simon: I know! He tried to murder us, didn't he? That's sort of the definition of unfriendly: "Tries to kill you with a bow and arrow".
Unfriendly by Yogscast fan November 10, 2012

Unfriendly Black Hottie 

An African American person who is very attractive but is very mean to people outside their immediate friend group. An example of this is in the movie mean girls.
Chad: Damn Keisha is so hot!

Mason: Dude she’s an unfriendly black hottie you don’t have a chance with her.