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This phrase is never meant to be taken literally. No-one really injects coffee directly into their blood stream. Caffeine is the main ingredient of coffee, and gives us a feeling of satisfaction. It is simply a joking expression which refers to an intense love, or even addiction, to coffee.
I'm going nuts - If I don't shoot caffeine intravenously soon I'm going to fall out of my tree!

When I was 13 I had my first coffee, and I've been practically shooting caffeine intravenously ever since!
by Brother Ramon July 8, 2011
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Shooting Mars

It's when you aim a gun at Mars and shoot
"Hey, what are you up to?"
"Not much just shooting Mars, how about you?"
"Not much was just wondering what you were up to"
by CH L L L I N December 19, 2006
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Shooting the gap

Verb;

Shooting the Gap refers to when one has the beegees and is sitting on the toilet releasing a massive amount of watery feces then suddenly they have to barf so they must "shoot the gap" between their privates and the bowl.
after a long night of burritos and liquor Kevin ran to the shitter and ended up shooting the gap. he barf all over his balls
by Jonnoguano August 6, 2011
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shooting the walrus

I haven't released in a week, i really need to shoot the walrus.
by walrus December 5, 2003
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Shooting the moon

right before u cum u pull your dick out and pop some gizz over her (or even him)see kyle redding
right before kyle gizzed he pulled his dick out of chets ass and cummed on his head and on the floor
by the project pat June 1, 2004
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shooting the shit

We were just shooting the shit at the bar.
by Shaner October 27, 2003
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shooting the shit

we were shooting the shit when we were bored
by Anonymous October 29, 2003
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