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exfoliate 

Actually means to clean yourself in such a way to remove dead skin cells and then remoisturize the skin.

Now that the real definition is out of the way, let's do an Urban definition!

When a man is pounding a chick doggy-style near a toilet. The man grabs the chick by the hair and shoves her head into the toilet, flushing it and giving her a swirley! Now that the face is cleansed, it must be moisturized. The guy then yanks her head out of the the toilet by her dripping wet hair, pulls his dick out of her, and blows his load all over her face.
I'll exfoliate Mel Gibson, how 'bout that?

exfoliate 

This new soap has shards of glass in it, so it really exfoliates.
exfoliate by BubDZombie July 10, 2009

Sexfoliation

Sexfoliation can be achieved through sex.
Sexfoliation by Amonomous September 29, 2010

exfoliate 

To come out of a shell and do something different to express yourself.
From "What Women Want" (Mel Gibson and his screen daughter in bathroom, Mel in pantyhose)

Daughter: "Dad! What are you doing??"
Mel: "I'm...ah...exfoliating"
exfoliate by SuperMan9856 March 14, 2004

Sexfoliation

The act of ejaculating on a loofa and using it to exfoliate a woman's face or body.
I used sexfoliation on my girlfirends face in the shower and her acne cleared up in an hour!
Sexfoliation by Plausible March 8, 2009

exfoliate 

The getting under of the skin which a person does that causes their girlfriend or boyfriend to become an ex girlfriend of boyfriend.
"You have to give me some facts so that I can defend myself."
"No, I don't."
"Well then, good luck to you and the kids."
"Good luck to being exfoliated."