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This is easy for anyone with a basic knowledge of history. A Texican, or a Texian, were both mid-19th century words for American colonists to Texas.

In contrast, a Tejano was a Texan of Mexican origin. Simple as that. All this other nonsense posted here is just that.
Texicans and Tejanos alike rebelled against the Mexican Government
Texican by pjnevada August 23, 2011
Related Words
A person living in Texas during the time of the Republic of Texas.

A person modern who advocates that Texas secede from the United States.
The Texicans sought entry of Texas into the United States as a way to repay war debts and ensure that Mexico would not attempt to reclaim their former territory.

Senator Smith is running on a Texican platform, claiming that Texas contributes more to the United States that the state receives in return.
texican by johntex December 8, 2004
A native Texan of Mexican descent.
He's a second-generation Texican.
texican by DT October 5, 2003
Los Lonely Boys describe themselves as Texicans.
texican by Phlip June 29, 2004

texican't 

a grossly over-weight Texan with a thick southern drawl, a rifle in his hand, and a bible that he believes every word of yet hasn't read a word of.......he tends to like to go to war, hate homosexuals, demean women, commit verbal hate crimes, and complain about what the queers are doing to the soil.
that god damn texican't is at it again.

you are so dumb you must be a texican't.
texican't by CurvedMirror July 2, 2008
A Texican is person of european decent in Texas. A Tejano is a person of hispanic decent in Texas
I'm a Texican. My ancestors are German and Irish.
texican by RealTexican April 9, 2006