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1.
Innocent or naive.
The doe-eyed freshmen did not realize how hard their first school year would be.
by CBruer September 06, 2009
 
2.
some women, like does, have beautiful brown eyes
Winona Ryder, a doe-eyed actress
by Mig March 15, 2004
 
3.
Josie McCoy from "Josie and the Pussycats".

She is the very DEFINITION of the word.

More accurately, it is the actor that portrays Josie, Rachael Leigh Cook, who is the "doe-eyed beauty". But it's this movie that accentuates her big brown eyes the most.
Rachael Leigh Cook is a doe-eyed beauty
Josie McCoy is a doe-eyed beauty
by crazyforRLC April 26, 2004