1. The moment at which Templeton "Face" Peck of the A-Team must use his masculine charms, usually (though not necessarily limited to) upon an attractive female with large hair, in order to gain access to a building or otherwise perform some smooth-patter feat to ensure the success of the on-the-run ex-military samaritan squad.
2. The first, prolonged, intimate session of sexual contact with Templeton "Face" Peck of the A-Team, usually no more than half an hour after an episode's closing credits.
Hannibal: "Face, we need you to distract that womanly security guard in order to steal that kettle to make our steam tank."
Templeton "Face" Peck: "OK, it's Face Time."
Attractive big-haired 80s woman: "Templeton, what are you...?"
Templeton "Face" Peck: "Oh yeah momma, it's Face Time..."