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Pwntacular is used for something that goes beyond pwn - it is used for something, usually in video games, that is so extraordinary, that it deserves this word.
"Oh my god! We beat those guys ten times in a row...without losing any health! Pwntacular!"

"I killed that loud mouth seventeen times in a row...with a plasma pistol. Pwntacular."
by Slayer02 December 31, 2005
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