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This word is comprised of two parts:
Exo: outer, as in exoskeleton
Think: that's what you did while processing the word 'think' and what you're doing now digesting this definition.

Exothink: to think outside of prefabricated parameters to reach a logical conclusion or to solve problems, to think "outside the box"
(Perhaps also: creative critical thinking)

As a noun: Exothinkerton (singular) or Exothinkers (plural)
Exothink to circumvent approaching obstacles when all traditional approaches fail.

Engineers are great exothinkers

Why didn't I think of that? You're such an exothinkerton.

The solution was an exothought that deviated from the standard adherence to Murphy's Law.

by soup?oh!nom December 22, 2016
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