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1.
A state of absolute hunger in which one can no longer make rational decisions. For example, being so "starving" that one overlooks the fact his/her pizza has been under the couch for 2 weeks.
Used for dramatic effect in less serious circumstances.
God damn, I'm so starvacious my stomach is eating itself in its own juices.

I gotta hit up a McD's, I'm so fucking starvacious!
by Jerry Begone July 14, 2005
 
2.
So hungry that you are starving
"I don't care where we go to eat. I haven't eaten since breakfast and I'm starvacious.
by Word girl August 10, 2014