It's the name of the soccer player from Spain who headed a nice goal against Germany in the World Cup 2010 Finals. It can be used as a verb to mean giving it your ALL, to rally, to push hard. This Puyol goal was AMAZING and this should become a verb. His goal was the only one in the game and put Spain in the Finals!
I was so tired but puyoled myself together and puyoled a sprint at the end of the race.
I was trying to defend myself but he was puyoling (hard). *here, hard is just a big underlining. It is almost redundant because to puyol is to push hard anyway!