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Definitions by Xim, the Poisonous bitch.

Pick me ass bitch. 

Pick me ass bitch is someone who likes to act like everyone else in hope that they'll gain a friend/boyfriend/girlfriend. Tries too hard to be everyone's friend. Always underneath someone's ass and is willing to make others look dumb just to be around someone's company.
Him: Who here is a virgin?
Her: Me, I've never even sucked dick before.
Another guy:That's a pick me ass bitch.