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1.
To make a negative comment towards someone; to diss.

(The releasing of comments made to injure.)
Sean: My sneakers are fly as hell
Jay: I may have seen chickens flying higher than your shoes
Sean: Yo, stop throwing shots.
by lemonysalt February 22, 2012
 
2.
A situation where, knowingly or unknowingly, a female sits on a chair and her skirt rides high enough on her leg so as to allow others to see her underwear.
From time to time in high school, boys would be on the lookout for Cindy sitting in the cafeteria because she would be throwing shots.
by flugerman February 12, 2007