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1.
To perform anal intercourse on someone, dilating the rectum in the process. Afterwards the performer repositions the rectum, by spreading the anus with their hands. Giving the stretched rectum a kiss. The dilated, stretched rectum resembles a red star. Furthermore, the name is inspired by the Dairy Queen ice cream starkiss
My old lady told me for her birthday she'd rather get star kissed instead of going to Dairy Queen.
by Ithadtobedoneandone February 29, 2012
 
2.
A star kiss is the mark left in underwear or the sheets after coming in contact with the stink star.
Dude, I sat on my bed after I got out of the shower and left a star kiss on the sheets.
by Bubba cop November 10, 2008