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1.
A derogatory term used to talk about people of Hispanic descent.

It was recently said in an episode of “The Shield”
Look at that chili shitter
by stothectotheotothett February 02, 2006
 
2.
Illegal Mescans from Mexico. Friends of George Bush.
The Rio Grande border towns in Texas are full of chili shitters trying to get farther inland to find a job.
by Richard Black March 12, 2005