Getting "sniped" by a USAF E-7 through E-9 for minor, temporary, or transitionary uniform infractions. Often, you will be alone, and they will come out of a dark space to correct you, or they will crawl out of a man hole. Alternate definition: the end result of too much overhead at a deployed location.

To smoke weed, derived from passing the peace pipe around, native american style.

a Bostonism, used ironically in a freindly way to point to idiotic behavior
This is the source for the fictional "Charlestown Chiefs" hockey team in the movie SLAPSHOT

when a girl is a straight dime or when a specific body part of a girl is just amazing.

For one to be recognised as a "chief" you must either be a cocky and brash "know-it-all" or you do things or say things at unappropriate times.

(verb) to chief: to smoke marijuana, pot, refer, or bud. This is called "chief" because the indians smoked lots of tobacco and various marijuana plants and the Chief always got the first drag. This word was revibed and defined by Bobbles of NYC.

someone who wants to be in charge but has no idea what they are doing
It is a dirrogatory term(insult)