This is the "D'oh Face" emoticon. The capital X representing Homer Simpson's squinting eyes and the small "o" to represent the shape of his mouth as he exclaims, "D'oh!"
Alternately it can appear as: X0 or Xo!
It is meant to be distinct from XO, which represents kiss and hug—so be careful.
I spoke too soon when I declared that I was "King of the World." Xo
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