The act of ejaculating on a girls face so much and in all different directions that it appears to be a spiderweb. Sometimes leading to the girl saying "I CAN'T SEE!!!" or "IT'S BURNING MY EYES!!!"

When one ejaculates onto his hand, then in a swift motion, creates the web shooting hand sign as spiderman does, and in the process, "shooting the web" at your ho causing her to be in a "sticky" situation.