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1.
Describes when someone or something is a severe bitch or pain the ass. It can also be used to express misfortune or anger like damn or fuck, or as a random vulgar adjective that serves no purpose but to add crudeness to a sentence.
"This knee injury is such a shit ass bitch."

"What the shit ass bitch are you doing on Friday night?"

"Awwwww, shit ass bitch!"
by Captain Benjamin April 18, 2007
 
2.
A ridiculous word, comparable to omgwtfbbq to reflect humorous anger
"hey i stole your last monster, oh wait it was your mom :)
"SHITASSBITCH!"
by shitassbitch June 20, 2009