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1.
A term often heard in movies from the 1930's, 40's, and 50's, a "pie face" is an extraordinarily pretty girl.
Rosalind Russell to Cary Grant in "His Girl Friday": "You wouldn't have hired me if I wasn't pie-faced."

She's a pie face.

What a pie-faced babe.

Who's the pie face?
by Great Sage Equaling Heaven January 02, 2009
 
2.
A derogatory term for Asians, for their lack of a facial profile (flat-faced) but accounting for obvious raised facial features (nose, lips).
A banana cream pie held up flat face pie-face pie face
by yeahthatswhy February 12, 2010
 
3.
The name given to the facial area of a person who has an abnormally large and round face. As implied in the name, the circular face will resemble a pie, or a perfect circle drawn carefully with a compass in maths. A person with a pie face is likely to be mocked incessantly by 'friends', and subsequently may find it hard to talk to people without them thinking they are talking to a floating pastry.
'Good heavens, have you seen how round Emma's face is?!'
'Yeah, massive pie face.'
by suckmahdick101 March 25, 2010
 
4.
To take ones hand and push another person's face.

An open hand, covering another perons face like you threw a pie at them.
Mark was being a jerk, so I piefaced him and he fell to his knees.
by Dean November 12, 2004
 
5.
usually a term associated with asian people. but is actually supposed to be used with Alaskan people.
I'm in the mood for some pie face food
by Pimpster McSpankable January 21, 2003
 
6.
Best ska band ever. They make the most fucking rad music. You haven't lived until you've let their audio-sensory sweet nectar drip down and enhance your eardrum. The name was not made by Tom Sullivan.
"Hey man Streetlight Manifesto played at my house last night it was awesome!"
"Yeah whatever. I saw a Pieface show."
"Aw fuck. You lucky bastard."
by ShittyFatTits August 22, 2011
 
7.
someone whos face is so fat that it looks like a pie
a fat boy
by jim June 14, 2003