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1.
Used to describe someone who is actually hot, usually used in conjunction with work hot.
Dude 1: Damn, you should see the receptionist at the client I went to today!

Dude 2: Is she work hot?

Dude 1: No, she's hot hot!

Dude 2: Nice! I'm gonna go perform some "emergency maintenance" on her PC!
by Capt. Underpants October 12, 2007
 
2.
Hot 100, a cinnamon flavored liquor that comes in plastic flasks. The consumption of an entire bottle usually makes a person get petey fairly quickly.
"I wanna get hammed tonight, I'll drink this Hot Hot!"
by MinnesotaMarge March 20, 2006