Gymprovisation comes in two forms:
A) a hotel or other gym with a limited selection might require you to gymprovise in one way or another.
B) you might be such a workout freak that you need to gymprovise to hit that muscle "just right".
You should be careful with option B because it can come across as douchy.
Jane: Yeah, he must use gymprovisation to get a body like that.