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1.
The final injection a herion user takes before he or she ODs
John: "I saw her lying in a pool of vomit and vaginal discharge as she injected herself just before she died."

Jim: "Ahh, the golden shot"
by jseps March 07, 2011
 
2.
when a man urinates in someones mouth.
"Kenny wane game his son the golden shot"