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1.
An ice cream consisting of three segregated flavours of vanilla, strawberry, and chocolate, and is quite possibly the best ice cream ever conceived. The use of Napoleon over the word neopolitan (the official name of the ice cream) is a much more chic way of referring to it.
I can't wait to go to Tanpopo tonight. I am going to have three, no, FOUR bowls of Napoleon Ice Cream.
by Samdog III February 21, 2006
 
2.
When two women of european and african ancestry engage is rubbing their vaginas against each other or "scissor". Thus creating the color affect of vanilla and chocolate on either side with strawberry in the middle.
"Dude I was watching this porn and they had these two broads doing the Napoleon Ice Cream. It was so hot."