A woman who, despite her face, is still very attractive and fair game. Not to be confused with butter faces, these women are still desirable. Where as butter face starts with the positive (hot body) and ends with the negative (her face), d'spiter face is a term that maintains a positive attitude.
Donny: Hey, Rude, check out that pair of tits down the street.
Rudy: Man, take a better look
Donny: No, bro. You got it all wrong. She's a d'spiter face.